| 1 | Schleck, Frank | Team CSC | 6:25:39 |
| 2 | Wesemann, Steffen | T-Mobile Team | a 22" |
| 3 | Boogerd, Michael | Rabobank | a 46" |
| 4 | Kroon, Karsten | Team CSC | a 48" |
| 5 | Sinkewitz, Patrik | T-Mobile Team | a 48" |
| 6 | Rebellin, Davide | Gerolsteiner | a 48" |
| 7 | Martin Perdiguero, Miguel Angel | Phonak Hearing Systems | a 48" |
| 8 | Bettini, Paolo | Quickstep - Innergetic | a 53" |
| 9 | Schumacher, Stefan | Gerolsteiner | a 57" |
| 10 | Ivanov, Sergei | T-Mobile Team | a 1'07" |
| 11 | Ballan, Alessandro | Lampre - Fondital | a 1'12" |
| 12 | Moos, Alexandre | Phonak Hearing Systems | a 1'12" |
| 13 | Wegmann, Fabian | Gerolsteiner | a 1'12" |
| 14 | Etxebarria Alkorta, David | Liberty Seguros - Würth Team | a 1'12" |
| 15 | Sanchez Gonzalez, Samuel | Euskaltel - Euskadi | a 1'20" |
| 16 | Moletta, Andrea | Gerolsteiner | a 1'22" |
| 17 | Freire Gomez, Oscar | Rabobank | a 1'25" |
| 18 | Moreni, Cristian | Cofidis, le crédit par téléphone | a 1'25" |
| 19 | Dekker, Thomas | Rabobank | a 1'25" |
| 20 | Horner, Chris | Davitamon-Lotto | a 1'30" |
| 21 | Kessler, Matthias | T-Mobile Team | a 1'33" |
| 22 | Zaballa Gutierrez, Constantino | Caisse d´Epargne - Illes Balears | a 1'34" |
| 23 | Valverde Belmonte, Alejandro | Caisse d´Epargne - Illes Balears | a 1'34" |
| 24 | Grivko, Andriy | Team Milram | a 1'36" |
| 25 | Bertagnolli, Leonardo | Cofidis, le crédit par téléphone | a 1'36" |
| 26 | Aerts, Mario | Davitamon-Lotto | a 1'49" |
| 27 | Astarloa, Igor | Barloworld | a 1'53" |
| 28 | Elmiger, Martin | Phonak Hearing Systems | a 2'54" |
| 29 | Sørensen, Nicki | Team CSC | a 2'54" |
| 30 | Van Den Broeck, Jurgen | Discovery Channel Pro Cycling Team | a 2'54" |
| 31 | Vasseur, Cedric | Quickstep - Innergetic | a 2'54" |
| 32 | Moerenhout, Koos | Phonak Hearing Systems | a 2'54" |
| 33 | Voeckler, Thomas | Bouygues Telecom | a 2'54" |
| 34 | Jalabert, Nicolas | Phonak Hearing Systems | a 2'54" |
| 35 | Stangeij, Gorazd | Lampre - Fondital | a 2'54" |
| 36 | Garzelli, Stefano | Liquigas | a 2'54" |
| 37 | Fofonov, Dmitri | Crédit Agricole | a 2'54" |
| 38 | Brandt, Christophe | Davitamon-Lotto | a 2'54" |
| 39 | Den Bakker, Maarten | Team Milram | a 2'54" |
| 40 | Bellotti, Francesco | Crédit Agricole | a 2'54" |
| 41 | Dumoulin, Samuel | AG2R Prévoyance | a 2'54" |
| 42 | Ten Dam, Laurens | Unibet.com | a 2'54" |
| 43 | van Summeren, Johan | Davitamon-Lotto | a 2'54" |
| 44 | Iglinskiy, Maxim | Team Milram | a 2'54" |
| 45 | Commesso, Salvatore | Lampre - Fondital | a 2'54" |
| 46 | Leukemans, Bjorn | Davitamon-Lotto | a 2'54" |
| 47 | Tjallingii, Maarten | Skil - Shimano | a 2'54" |
| 48 | Van Huffel, Wim | Davitamon-Lotto | a 2'54" |
| 49 | Mori, Manuele | Saunier Duval - Prodir | a 2'54" |
| 50 | Carlström, Kjell | Liquigas | a 2'54" |
| 51 | Gusev, Vladimir | Discovery Channel Pro Cycling Team | a 2'54" |
| 52 | Pozzato, Filippo | Quickstep - Innergetic | a 2'54" |
| 53 | Mancebo Perez, Francisco | AG2R Prévoyance | a 2'54" |
| 54 | Azevedo, José Bento | Discovery Channel Pro Cycling Team | a 2'54" |
| 55 | Mazzoleni, Eddy | T-Mobile Team | a 2'54" |
| 56 | Tankink, Bram | Quickstep - Innergetic | a 2'54" |
| 57 | Merckx, Axel | Phonak Hearing Systems | a 2'54" |
| 58 | Paolini, Luca | Liquigas | a 2'54" |
| 59 | Figueras, Giuliano | Lampre - Fondital | a 2'54" |
| 60 | Kirchen, Kim | T-Mobile Team | a 2'54" |
| 61 | Chavanel, Sylvain | Cofidis, le crédit par téléphone | a 5'31" |
| 62 | Cheula, Gian Paolo | Barloworld | a 5'31" |
| 63 | Perez Arrieta, Aitor | Caisse d´Epargne - Illes Balears | a 5'31" |
| 64 | Devolder, Stijn | Discovery Channel Pro Cycling Team | a 5'47" |
| 65 | Joachim, Benoit | Discovery Channel Pro Cycling Team | a 5'47" |
| 66 | Coenen, Johan | Unibet.com | a 5'47" |
| 67 | Vierhouten, Aart | Skil - Shimano | a 5'47" |
| 68 | Blaudzun, Michael | Team CSC | a 5'47" |
| 69 | Gilbert, Phillippe | Française des Jeux | a 5'47" |
| 70 | Haussler, Heinrich | Gerolsteiner | a 5'47" |
| 71 | Wilson, Matt | Unibet.com | a 5'47" |
| 72 | Sacchi, Fabio | Team Milram | a 5'47" |
| 73 | Baguet, Serge | Quickstep - Innergetic | a 5'47" |
| 74 | Schröder, Björn | Team Milram | a 5'47" |
| 75 | Caucchioli, Pietro | Crédit Agricole | a 5'47" |
| 76 | Marzano, Marco | Lampre - Fondital | a 5'47" |
| 77 | Facci, Mauro | Barloworld | a 5'47" |
| 78 | Isasi Flores, Inaki | Euskaltel - Euskadi | a 5'47" |
| 79 | Weening, Pieter | Rabobank | a 5'47" |
| 80 | Zberg, Markus | Gerolsteiner | a 6'02" |
| 81 | Vicioso Arcos, Angel | Liberty Seguros - Würth Team | a 6'10" |
| 82 | Calcagni, Patrick | Liquigas | a 6'10" |
| 83 | Camano Ortuzar, Iker | Euskaltel - Euskadi | a 6'10" |
| 84 | Pasamontes Rodriguez, Luis | Unibet.com | a 6'10" |
| 85 | Voigt, Jens | Team CSC | a 6'10" |
| 86 | Arroyo Duran, David | Caisse d´Epargne - Illes Balears | a 6'10" |
| 87 | Bertoglitiati, Rubens | Saunier Duval - Prodir | a 6'31" |
| 88 | Musiol, Daniel | Team Milram | a 6'31" |
| 89 | Sabido, Hugo | Barloworld | a 6'31" |
| 90 | Langeveld, Sebastiaan | Skil - Shimano | a 6'31" |
| 91 | Poilvet, Benoît | Crédit Agricole | a 6'31" |
| 92 | Beneteau, Walter | Bouygues Telecom | a 6'31" |
| 93 | Kaggestad, Mads | Crédit Agricole | a 6'31" |
| 94 | Bessy, Frederic | Cofidis, le crédit par téléphone | a 6'31" |
| 95 | Renders, Sven | Landbouwkrediet - Colnago | a 6'31" |
| 96 | Ghyllebert, Pieter | Chocolade Jacques - Topsport Vlaanderen | a 6'31" |
| 97 | Rodriguez Oliver, Joaquin | Caisse d´Epargne - Illes Balears | a 18'11" |
| 98 | Serrano Rodriguez, Marcos Antonio | Liberty Seguros - Würth Team | a 18'11" |
| 99 | Albizu Lizaso, Joseba | Euskaltel - Euskadi | a 18'11" |
| 100 | Lobato Elvira, Ruben | Saunier Duval - Prodir | a 18'11" |
| 101 | Kashechkin, Andrey | Liberty Seguros - Würth Team | a 18'11" |
| 102 | Engels, Addy | Quickstep - Innergetic | a 18'11" |
| 103 | Grabsch, Bert | Phonak Hearing Systems | a 18'11" |
| 104 | Casar, Sandy | Française des Jeux | a 18'11" |
| 105 | Cox, Ryan | Barloworld | a 18'11" |
| 106 | Thijs, Erwin | Unibet.com | a 18'11" |
| 107 | Gomez Marchante, José Angel | Saunier Duval - Prodir | a 18'11" |